“Toroud”, the late motion for As-Sb bearing Cu production from 2nd millennium BC in Iran : an archaeometallurgical approach
Part of : Mediterranean archaeology & archaeometry : international journal ; Vol.14, No.2, 2014, pages 185-204
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Pages:
185-204
Author:
Abstract:
The interest in arsenic copper and its use in antiquity is on a speedy rise. The potential values of such commodity have drawn significant attention. According to many literatures that will be presented throughout this paper, there is great evidence, that real tin bronze replaced arsenic bronze during 2350-2200 B.C. in the central plateau of Iran. "Chah-Messi" copper mine could be a key point of such investigations. Indeed, multimelange metallic outcrops made this region to a great metallogenic zone. Archaeometallurgical investigations based on geological survey in “Chah-Messi” copper mine in northern part of the central Iranian desert indicate that during the 2nd millennium BC ancient mining and metallurgy were carried out because of outcropping of hydrothermal copper mineralization. The main point of this work focuses on the characterization of the extractive slags with respect to the Cu-As-Sb bearing minerals.Mineralogical-petrochemical studies have been carried out via reflected- and transmitted light microscopy including electron probe microanalyser (EPMA) to perform the analysis of the chemical composition of phases. Based on the results, the material proved to have high amount of Cu, CaO and iron oxide and low in MgO, MnO. Furthermore the result of this study indicated that the Chalcosite and covellite were the processed ore. Lauzonite (Cu-As-Sb) and domeykite (Cu-As) were the dominant Cu-As-Sb bearing minerals which could have the primary influence on the smelting processes and composition of extracted metal. Such characteristics are the hall mark of this region.
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Keywords:
archaeometallurgy, copper, slag petrology, As-Sb mineralization, electron probe microanalysis, Chah-Messi, Toroud
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Περιέχει 19 εικόνες και 3 πίνακες.
References (1):
- Burnol, L. (1968) Contribution a l' etude de gisemnts de plomb et zinc de l' Iran, Tehran, Iran: Geological Society of Iran Report.Craddock, P. (1986) The Metallurgy and Composition of Etruscan Bronze, Studi Etruschi, 52, 211–271Chegini, N.N., Helwing, B., Parzinger, H., and Vatandoust, A. (2004) A prehistoric industrial settlement on the Iranian Plateauereseach at Arisman, in: Stöllner, T., Slotta, R., Vatandoust, A. (Eds.), Persia’s Ancient Splendour; Mining, Handicraft and Archaeology. DeutschesBergbau-Museum, Bochum, pp. 210-217.De Ryck, I., Adriaens, A., and Adams, F. (2005) An overview of Mesopotamian bronzemetallurgy during the 3rd millennium BC, Journal of Cultural Heritage, vol. 6, 261–268Dyson Jr., R. H., and Voigt, M. M. (1989) Bronze Age, in E. Yarshater, Encyclopedia Iranica, vol. IV (pp. 472-478), London & New York: Routledge & Kegan Paul.Emami, M. A. (2005) Experimental and petrological studies of ancient slags to define the paragenesis of ore deposits, International Iranian Mining Engineer, Tehran, Iran: Ministry of Metals and Mining, pp. 63-78Emami, M. A. (2002) Mineralogische Untersuchungen zur Archaeometallurgie von Toroud, Iran. Deutschland-Mainz: Diplomarbeit, Fachbereich fuer Geowissenschaften der Universitaet Mainz (unpublished)Foerster, H. (1978) Mesozoic-Cenozoic metallogenesis in Iran, Journal of the geological society of Iran, vol. 4, 135, pp. 443-455.Frame, L. (2010) Metallurgical Investigations at Godin Tepe, Iran, Part I: The Metal Finds. Journal of Archaeological Science, 37, no. 7, pp. 1700–1715Frame, L.D. (2012) Reconstructing ancient technologies: Chalcolithic crucible smelting at Tal-i Iblis, Iran, in Jett, P., McCarthy, B., and Douglas, J.G. (eds.), Scientific Research on Ancient Asian Metallurgy: Proceedings of the Fifth Forbes Symposium at the Freer Gallery of Art, Archetype, London: 183–204Giumlia Mair, A. (2012) The Enkomi cup: niello versus kuwanu, in eastern Mediterranean Metallurgy and Metalwork in the second Millennium BC, Nicosia 10-11 Oct. 2009, edited by; Vasiliki Kassianidou and George Papasavvas, OXBOW BOOKS: 107-116Haptmann, A. (2007) The Archaeometallurgy of Copper, evidence from Faynan, Jordan, Natural Science in Archaeology, series editors: B. Herrmann, G. A. Wagner, Springer Verlag.Hauptmann A, Rehren, Th., and Schmitt-Strecker S. (2003a) Early Bronze Age Copper Metallurgy At Shahr-iSokhta (Iran), reconsidered, in: Stöllner T, Körlin G, Steffens G, Cierny J (eds) Man and Mining – Mensch und Bergbau. Studies in honour of GerdWeisgerber on occasion of his 65th birthday. Der Anschnitt, Beiheft 16, Deutsches Bergbau-Museum Bochum, pp 197–213Hauptmann, A. (1985) 5000 jahre Kupfer in Oman,Die Entwicklung der Kupfermetallurgie vom 3 Jahrtausend bis zur Neuzeit, Der Anschnitt , vol. 4, Bochum.Hezarkhani, Z., and Keesmann, I. (1996) Archaeometallurgische Untersuchungen an Kupferschlaken im Zentraliran, Metalla, vol. 3.2, pp.101-125Hole, F. (2000) New radiocarbon dates for Ali Kosh, Iran. neolithics, vol. 1, pp. 13-19Hooshmandzadeh, A., Alavi Naini, M., and Haghipour, A. (1978) Recently Geological Evidences in Toroud, Iran. Teheran: Geologica Survey of Iran.Keesmann, I., and Moreno Onorato, A. (1999) Naturwissenschaftlliche Untersuchungen zur fruehen Technologie von Kupfer und Kupfer-Arsen-Bronze, The beginning of Metallurgy, Der Anschnitt, Beiheft 9, 317-360Keesmann, I. (2005) Arche'ome'tallurgie de l'Iran Central - II. Les scories de cuivre: une comparsion, Cuivre+Bull. A.P.A.B. (Beaune) , vol 4.1, pp. 17-23Keesmann, I., Schulz-Dobrick, B., and Vierck, H. (1983) Chemische und mineralogische Untersuchungen der Schmiedeschlacken von Asperden, Fortschritt der Mineralogie 61 , vol. 1, pp. 110-111Keesmann, I., Bachmann, H., and Hauptmann, A. (1982) Norm-Berechnungsverfahren für eisenreiche Schlacken. Fortschritt der Mineralogie 60, 1:110–111Lechtman, H., and S. Klein. (1999) The production of copper-arsenic alloys (arsenic bronze) by cosmelting: modern experiment, ancient practice, Journal of Archaeological Science, vol. 26: 497-526Marechal, J. R. (1985) methods of Ore Roasting and the Furnace Used (Trans. by P.T. Craddock). In P.T. Craddock and M.J. Hughes (eds.), Furnace and Smelting Technology in Antiquity. British Museum Occ. Paper 48.29-42Matthews, R., and Fazeli, H. (2004) Copper and complexity: Iran and Mesopotamia in the fourth millennium, BC. Iran, 42, 61–75Maurer Thrinkhaus, K. (1986) Pottery from the Damghan Plain, Iran: Chronology and Variability from the Partian to the Early Islamic Periods, Studia Iranica, Tome 15, fasc. 1: 23-88Maurer Thrinkhaus, K. (1989) Archaeological Survey of the Damghan Plain, Northeast Iran, 1976-1977Momenzadeh, M. (2004) Metallische Bodenscha¨tze in Iran in antiker Zeit. Ein kurzer U¨ berblick, in T. Stoellner, R. Slotta, & A. Vatandoust (Eds.), Persiens antike Pracht: Bergbau–Handwerk–Archaeologie.Katalog der Ausstellung (pp. 8–21). Bochum: Deutsches Bergbau-MuseumMoorey, P. R. (1969) prehistoric Copper and Bronze Metallurgy in Western Iran (with special reference to Lurestan), Iran, vol. 7, pp. 131-153Mueller Karpe, M. (1990) Aspects of early metallurgy in Mesopoiamien, in E. Pernicka, & G. A. Wagner, Archaeometry, pp. 105-116Oudbashi, O., Emami, M. A., and Davami, P. (2012) Bronze in Archaeology: A Review of the Archaeometallurgy of Bronze in Ancient Iran in Copper Alloy (Chapter 7), In: Tech Publication, p. 154-178, ISBN: 978-953-308-35-6Pernicka, E. (2004a) Kupfer und Silber in Arisman und Tappeh Sialk und die fruehe Metallurgie in Iran. InT. Stoellner, R. Slotta, & A. Vatandoust (Eds.), Persiens antike Pracht: Bergbau–Handwerk–Archaeologie. Katalog der Ausstellung, Bochum: Deutsches Bergbau-Museum, pp. 232–239.Pigott, V. C. (1999) The development of metal production on the Iranian plataeu. An archaeometallurgical perspective,The archaeometallurgy of the Asian Old World , pp. Pigott, V. C. (Ed), vol. 7, pp. 73-106.Pigott, V. C. (1999) The development of metal production on the Iranian plataeu: an archaeometallurgical perspective. In (V. C. Pigott, Ed.). In The Archaeometallurgy of the Asian Old World, (pp. 73-106). Philadelphia: University Museums Series, university of Pennsylvania.Pigott, V. C., Howard, S. M., and Epstein, S. M. (1982) Pyrotechnology and culture change at Bronze Age Tepe Hisar (Iran). In T. A. Wertime, & S. A. Wertime, Early Pyrothechnology, The Evolution of the First Fire Using Industries, pp. 215-236Pigott, V. C., Rogers, H. C., and Nash, S. K. (2003) Archaeometallutgical investigations at Tal-e Malyan: the evidence for tin-bronze in the Kaftari phase, in N. F. Miller, & K. Abdi, Yeki Bud, Yeki Nabud, Philadelphia: University of Pennsilvania Museum of Archaeology, pp. 161-175.Pigott, V. C. (1999b) A heartland of metallurgy: Neolithic/Chalcolithic metallurgical origins on the Iranian Plateau, in A. Hauptmann, E. Pernicka, Th. Rehren, & U¨ . Yalc¸in (Eds.), The beginnings of metallurgy, Der Anschnitt, Beiheft 9, Bochum: Deutsches Bergbau-Museum, pp. 109–122Pigott, V. C. (2004) Zur Bedeutung Irans fuer die Erforschung praehistorischer Kupfermetallurgie, in T. Stoellner, R. Slotta, & A. Vatandoust (Eds.), Persiens antike Pracht: Bergbau–Handwerk–Archaeologie. Katalog der Ausstellung Bochum: Deutsches Bergbau-MuseumRadivojevi´c, M., Rehren, Th., Kuzmanovic-Cvetkovic, J., Jovanovic, M. and Northover, P. (2013) Tainted ores and the rise of tin bronzes in Eurasia, c. 6500 years ago, Antiquity, vol. 87, p. 1030-1045Radivojevic, M. and Reberts, B. (2013) The rise of metallurgy in Eurasia, Historical metallurgy society news, issue 82, p. 4-5Rehren, T., Boscher, L., and Pernicka, L. (2012) Large scale smelting of speiss and arsenical copper at Early Bronze Age Arisman, Iran, Journal of Archaeological Science, vol. 39,pp. 1717-1727.Roustaei, K. (2010) Tepe Hesar, once again, Proceedings of the 6th International Congress on the Archaeology of the Ancient Near East, May, 5th-10th 2008, “Sapienza” - Università di Roma, Volume 2, Excavations, Surveys and Restorations:Reports on Recent Field Archaeology in the Near East, Edited by Paolo Matthiae, Frances Pinnock, Lorenzo Nigro and Nicolò Marchetti, 615-632Roustaei, K. (2012) Archaeo-Metallurgical Reconnaissance of Ancient Mines and Slag Sites on the Northern Edge of the Dasht-E Kavir Desert, Iran. Iranica Antiqua, vol. 47, P. 351Schreiner, M., Heimann, R. B., and Pernicka, E. (2003) Mineralogical and geochemical investigations into prehistoric smelting slags from TepeSialk/Central Iran,in Archaeometallurgy in Europe, Proceedings of the International Conference 24–26 September 2003, Milan: Associazione Italiana di Metallurgia, pp. 487–496Stöllner, T. (2004) Prähistorischer Und Antiker Erzbergbau in Iran, in Persiens Antike Pracht, edited by T. Stöllner, R. Slotta, and A. Vatandoust, 44–63. Bochum: Deutsches Bergbau-Museum, 2004.Stöllner, Th. (2003) Mining and Economy – A Discussion of Spatial Organisation and Structures. In: Stöllner T, Körlin G, Steffens G, Cierny J (eds) Man and Mining – Mensch undBergbau. Der Anschnitt, Beiheft 16, Deutsches Bergbau-Museum Bochum, pp 415–446Ströbele, F., Wenzel, Th., Kronz, A., Hildebrandt, L.H., and Markl, G. (2010) Mineralogical and geochemical characterization of high-medieval lead–silver smelting slags-fromWiesloch near Heidelberg (Germany)—an approachto process reconstruction. Archaeological and Anthropological Science, 2:191–215Thornton, C. P. (2010) The Rise of Arsenical Copper in South eastern Iran, Iranica Antiqua 45: 31–50Thornton, C. P. and Roberts, B. W. (2009). Introduction: The Beginnings of Metallurgy in Global Perspective, Journal of World Prehistory, Vol. 22, pp., 181-184.Thornton, C. P., and Ehlers, C. B. (2003) early brass in the ancient Near East, Institute for Archaeo-Metallurgical Studies, vol. 23, p. 3-8Thornton, C. P. (2009) The Emergence of Complex Metallurgy on the Iranian Plateau: escaping the Lavantine Paradigm. Journal of World Prehistory, vol. 22, pp. 301-327Thornton, C. P., and Rehren, T. (2009) A truly refractory crucible from fourth millennium Tepe Hissar, Northeast Iran, Journal of Archaeological Science, 2700-2712.Thornton, C. P., Lamberg-Karlovsky, C., Liezers, M., and Young, M. M. (2002) On Pins and Needles: Tracing the evaluation of copper-base alloying at Tepe Yahya, Iran via ICP-MS analysis of common-place items. Journal of Archaeological Science, vol. 29, pp. 1451-1460Thornton, C.P., Rehren, Th., and Pigott, V.C. (2009) The production of speiss (iron arsenide) during the Early Bronze Age in Iran. Journal of Archaeological Science, vol. 36, 308-316.Tosi, M. (1989) The Distribution of Industrial Debris on the Surface of Tappeh Hesār as an Indication of Activity Areas: in Dyson, Howard (eds) 1989, pp. 25-34.Weisgerber, G. (1990) Montanarchaeologie. Grundzuege einer systematischen Bergbaukunde fuer Vor- und Fruegeschichte und Antike. Der Anschnitt, 42, 2-18Weisgerber, G., and Hauptmann, A. (1988) Early Copper Mining and Smelting in Palestine. The Beginning and use of Metals and Alloys (BUMA), pp. 52-62Wertime, T. A. (1964) Man's First Encounters with Metallurgy. Science, vol. 146, No. 3649Wertime, T. A. (1973). The beginnings of metallurgy: A new look. Science, 182, 875–887.
