Chemical and statistical analysis of Roman glass from several Noethwetsren Iberian archaeological sites

Part of : Mediterranean archaeology & archaeometry : international journal ; Vol.14, No.2, 2014, pages 221-235

Issue:
Pages:
221-235
Author:
Abstract:
A total 103 fragments of Roman glass tableware are studied, unearthed at 7 archaeological sites in the Northwest of the Iberian Peninsula, to establish both similarities and differences in their chemical composition. ICP Mass Spectrometry is used to characterize the chemical composition of: (i) major elements, so as to determine the type of glass; (ii) minor elements, added to improve the properties of the glass; and, (iii) trace elements, as indicators of the base raw material of the glass. Multivariate statistical studies are also used to establish links and significant differences between glass samples, shedding further light on knowledge of Roman glass manufacturing techniques in the Northwest of the Iberian Peninsula. Three main conclusions were achieved. (i) There are significant chemical differences between samples from Braga (Bracara Augusta, Portugal) and the other samples. (ii) These other samples may be sorted into three major groups according to their chemical constituents. (iii) Finally, the statistical analysis and the chemical composition of several glass fragments suggest they were found at some distance from their place of manufacture, requiring the reclassification of their archaeological site of provenance.
Subject:
Subject (LC):
Keywords:
Roman glass, tableware fragments, chemical analysis, chemometric analysis, Iberian Peninsula
Notes:
Περιέχει 5 εικόνες και 3 πίνακες.
References (1):
  1. Alarcão, J. and Alarcão, A. (1967) Vidros Romanos do Museu Arqueologico de Vila Vicosa, Conímbriga. VI, Universidade de Coimbra, Coimbra, 1 - 45.Brems, D. Ganio, M. Latruwe, K. Balcaen, L. Carremans, M. Gimeno, D. Silvestri, A. Vanhaecke, F. Muchez, P. and Degryse, P. (2013a) Isotopes on the beach, part I: strontium isotope ratios as a provenance indicator for lime raw materials used in Roman glass-making, Archaeometry, vol. 55, 214 - 234.Brems, D. Ganio, M. Latruwe, K. Balcaen, L. Carremans, M. Gimeno, D. Silvestri, A. Vanhaecke, F. Muchez, P. and Degryse, P. (2013b) Isotopes on the beach, part II: neodymium isotopic analysis for the provenancing of Roman glass-making, Archaeometry, vol. 55, 449 - 464.Carmona, N. Villegas, M.A. Castellanos, M.A. Montero, I. and García Heras. M. (2008) Análisis de vidrios romanos del yacimiento de la Dehesa de la Oliva (Patones, Madrid), Cerámica y vidrio, vol. VII, 319 - 328.Carmona, N. Villegas, M.A. Jimenez, P. Navarro, J. and Garcia-Heras, M. (2009). Islamic glasses from Al-Andalus. Characterisation of materials from a Murcian workshop (12th century A.D., Spain). Journal of Cultural Heritage vol 10, 439-445.Costagliola, P. Baldi, G. Cipriani, C. Pecchioni, E. and Buccianti, A. (2000). Mineralogical and chemical characterisation of the Medicean glass mosaic tesserae and mortars of the Grotta del Buontalenti, Giardino di Boboli, Florence, Italy. Journal of Cultural Heritage vol 1, 287-299.Da Cruz, M. (2009) O Vidro Romano no Noroeste Peninsular. Um olhar a partir de Bracara Augusta. Tesis Doctoral, Universidade do Minho, 316 pp.Degryse, P. and Schneider, J. (2008) Pliny the Elder and Sr-Nd isotopes: tracing the provenance of raw materials for Roman glass production. Journal of Archaeological Science, vol. 35, 1993 - 2000.Domínguez-Bella, S. and Jurado Fresnadillo, G. (2004) Análisis arqueométrico de los vidrios romanos de la Casa del Obispo (Cádiz), in M. J. Felíu (ed.), Avances en Arqueometría 2003, Universidad de Cádiz, Cádiz, pp. 129 - 137.Fleming, S.J. (1999) Roman Glass: Reflections on Cultural Change. Philadelphia: University of Pennsylvania. 220 pages.Foster H.E. and Jackson, C.M. (2009) The composition of “naturally coloured” late Roman vessel glass from Britain and the implications for models of glass production and supply. Journal of Archaeological Science, vol. 36, 189 - 204.Foster H.E. and Jackson, C.M. (2010) The composition of late Roman British colourless vessel glass: glass production and consumption”. Journal of Archaeological Science, vol. 37, 3068 - 3080.Freestone I.C. Ponting M. and Hughes M.J. (2002) The origins of Byzantine glass from Maroni Petrera, Cyprus, Archaeometry, vol. 45, 257 - 272.Freestone, I.C. (2006) Glass production in Late Antiquity and the Early Islamic period: a geochemical prospective, in M. Maggetti, and B. Messiga (eds.) Geomaterials in Cul-tural Heritage. Geological Society of London Special Publication, pp. 201 - 216.Fuentes, A. Paz-Peralta, J.A. and Ortiz Palomar, E. (eds.) (2001) Vidrio Romano en España. La revolución del vidrio soplado. Fundación Centro Nacional del Vidrio. La Granja de San Ildefonso, Segovia.García Giménez, R., Vigil de la Villa, R., Recio de la Rosa, P., Petit Domínguez, M. D. and Rucandio, M. I. (2005) Analytical and multivariate study of Roman age architectural terracotta from northeast of Spain, Talanta, vol. 65, 861 - 868.García Heras, M. Rincón, J. M. Jiménez, P. and Villegas, M.A. (2005) Pre-Roman coloured glass beads from the Iberian Peninsula: a chemico-physical characterisation study. Journal of Archaeological Science, vol. 32, 727 - 738.García Heras, M. Sánchez del Prado, M. D., Carmona, N. Tendero, M. Ronda, A. M. and Villegas, M.A. (2007) Analytical study of Roman glasses from Southeastern Spain. Archaeología Polona, vol. 45, 63 - 78.Gliozzo, E., Santagostino Barbone, A. and D’Acapito, F. (2013) Waste glass, vessels and window-panes from Thamusida (Morocco): grouping natron-based blue–green and colourless Roman glasses. Archaeometry, vol. 55, 609 - 639Gómez Tubío, B. Ontalba Salamanca, M. A. Ortega Feliú, I. Respaldiza, M.A. Amores Carredano, F. and González Acuña, D. (2006) PIXE-PIGE analysis of late Roman glass fragments”. Nuclear instruments and methods in Physics Research B, vol. 249, 616 - 621.Henderson, J. (2002) Tradition and experiment in first millennium A.D. glass production - the emergence of early Islamic glass technology in late Antiquity. Accounts of Chemical Research, vol. 35, 594 - 602La Delfa, S. Ciliberto, E. and Pirri, L. (2008) Behaviour of copper and lead as chromophore elements in sodium silicate glasses. Journal of Cultural Heritage, vol. 9, 117 - 122.Liritzis, I. Salter, C. and Hatcher, H. (1997) Chemical composition of some Greco-Roman glass fragments from Patras, Greece. European Journal of Pact, nº 45, I.2, 25-34.Marengo, E. Aceto, M. Robotti, E. Liparota, M.C., Bobba, M. and Pantó, G. (2005) Archaeometric characterisation of ancient pottery belonging to the archaeological site of Novalesa Abbey (Piedmont, Italy) by ICP–MS and spectroscopic techniques coupled to multivariate statistical tools. Analytica Chimica Acta, vol. 537, 359 - 375.Mirti, P. Pace, M. Malandrino M. and Negro Ponzi, M. (2009) Sasanian glass from Veh Ardasır: new evidences by ICP-MS analysis. Journal of Archaeological Science, vol. 36, 1061 – 1069.Newton, R.C. and Davison, S. (1996) Conservation of glass, Butterworth-Heinemann, Oxford.Petit-Domínguez, M.D. Soto, I.S., García, R. Silva, M.P. and Rucandio, I. (2013) Analytical information on the composition of Roman Glass from Braga (Portugal). Quaternary International, vol. 308-309, 140-147.Rincón, J. M. (1984) Análisis y microestructura de vidrios Romanos de Mérida y Segóbriga. Revista de Arqueología, vol. 43, 34 - 39.Sánchez de Prado, M.D. (1984) El vidrio Romano en la provincia de Alicante, Lucentum, vol. 3, 79 - 100.Sayre, E.V. and Smith, R.V. (1961) Compositional categories of ancient glass. Science, vol. 133, 1824 - 1826.Silvestri, A. Molin, G. and Salviulo, G. (2005) Roman and Medieval Glass from the Italian area: bulk characterization and relationships with production technologies. Archaeometry, 47: 797 - 816.