Verifying the reliability of historical sources through a mineralogical and petrographic approach : The case of the “black-green stone” from the Messina Cathedral (Sicily, Italy)

Part of : Mediterranean archaeology & archaeometry : international journal ; Vol.16, No.3, 2016, pages 79-91

Issue:
Pages:
79-91
Author:
Abstract:
The aim of this work is obtaining information on the provenance of some very peculiar green (or blackgreen) stones used both as façade and floor decorations in the Messina Cathedral. Historical sources and available literature data suggest that these materials could belong to the amphibolite of the Peloritani Mountains. In order to verify the true provenance, some stone samples were studied through various analytical methods (SEM-EDS, XRPD, XRF). The investigated specimens resulted to be metabasites showing pseudomorphic and vein textures, with relicts of olivine replaced by serpentine - forming a mesh textures - and orthopyroxene mostly altered to bastite. Pseudomorphic minerals are serpentine (lizardite and chrysotile), magnetite, amphibole (tremolite-actinolite series) and chlorite (talc-chlorite). These results demonstrate that the analysed green stones cannot belong to the amphibolite outcrop of the Peloritani Mountains. Otherwise, they show mineralogical and petrographic features very similar to those of “verde Calabria”, a rock typology largely exposed in the Northern Calabria area - belonging to the ophiolitic series - and widely used in the last century as building material.
Subject:
Subject (LC):
Keywords:
Messina Cathedral, green decorative stones, amphibolites, petrography, Calabrian ophiolitic series
Notes:
Περιέχει 8 εικόνες και 2 πίνακες
References (1):
  1. Bienvenu, P., Bougault, H., Joron, J.L., Treuil, M. and Dmitrief, L. (1990) MORB alteration: Rare earth elements/non rare earth hygromagmaphile element fractionation, Chemical Geology, Vol. 82, pp. 1-14.Bonardi, G., Giunta, G., Liguori, V., Perrone, V., Russo, M. and Zappetta, A. (1976) Schema geologico dei Monti Peloritani, Boll. Soc. Geol. It., Vol. 95, pp. 49-74.Bottari, S. (1929) Il duomo di Messina, Messina-Bruker (2015a) Product overview: advanced analytical solutions.Bruker (2015b) XRF lab report - S8 TIGER plus GEO-QUANT M.Di Bella, M., Giuliano, A., Sabatino, G. and Triscari, M. (2010) Peculiar medieval floor decorations and artefacts from the town of Messina. In proceedings of A.I.Ar. Meeting, Pavia, February, Italy, pp 15-18.Giuliano, A. (2012) Una significativa novità sulle origini del Duomo di Messina in “Archivio Storico Messinese” n. 93, Messina 2012.Giuliano, A. (2015) Il ritrovamento dell’antica soglia del Duomo di Messina ed altro ancora. In: “IV Corso di aggiornamento per insegnanti e guide turistiche” Museo Regionale di Messina, 11 febbraio 2015.Hey, M.H. (1954) A new review of the chlorites. Min. Mag., Vol. 30, pp. 1-277.Leake, B.E. et al. (1997) Nomenclature of amphiboles: report of the subcommittee on amphiboles of the international mineralogical association, commission on new minerals and mineral names, The Canadian Mineralogist, Vol. 35, pp. 219-246.Compagnoni, R., Giacobbe, A. and Russo, S. (1995) Pre-Alpine poly-metamorphism in a new thrust sheet of the Calabrian-Peloritan Arc: Mela Unit. In: Proceedings of SIMP, Meeting, Venezia, September, Italy 1995; Vol. 14, pp. 225-226.Messina, A., Giacobbe, A., Perrone, V. and De Francesco, A.M. (1997) The Mela Unit: a new medium-grade metamorphic unit in the Peloritani Mts. (Calabrian-Peloritan Arc, Italy), Boll. Soc. Geol. It., Vol. 115, pp. 1-16.Principato, A. and Triscari, M. (1999) Tappeti marmorei pavimentali in provincia di Messina. In: Proceedings of F.I.S.T., Meeting, Bellaria, Italy, Vol. 22, pp. 314-316.Pouchou, J.L., Pichoir, L. (1986) Les éléments très légers en microanalyse X – Possibilités des modèles récents de quantification, J. Microsc. Spectrosc. Electron., Vol. 11, pp. 229-250.Pouchou, J.L. and Pichoir, L. (1984) Possibilités d’analyse en profondeur à la microsonde électronique, J. Microsc Spectrosc Electron, Vol. 9, pp. 99-100.Punturo, R., Fiannacca, P., Lo Giudice, A., Pezzino, A., Cirrincione, R., Liberi, F. and Piluso, E. (2004) Le cave storiche della “Pietra Verde” di Gimigliano e Monte Reventino (Calabria): studio petrografico e geochimico, Boll. Acc. Gioenia Sc. Nat., Vol. 37, pp. 35-57.Punturo, R., Bloise, A., Critelli, Catalano, Fazio and Apollaro (2015) Environmental Implications Related to Natural Asbestos Occurrences in the Ophiolites of the Gimigliano-Mount Reventino Unit (Calabria, Southern Italy), Int. J. Environ. Res. , Vol. 9, pp. 405-418.Rodolico, F. (1946) Le pietre delle città di Italia. Ed. Le Monnier. Italy, Firenze.Spadea, P. (1979) Contributo alla conoscenza dei meta basalti ofiolitici della Calabria settentrionale e centrale e dell’Appennino Lucano, Rendiconti della Società Italiana di Mineralogia Petrologia, Vol. 35, pp. 251–76.Stagno, F. and Zipelli, C. (1985) Risorse naturali del territorio messinese utilizzate in passato. Le "pietre nere" (petri nigri) delle fasce nel prospetto del Duomo di Messina. In Atti Acc. Peloritana Pericolanti, pp. 63-23.Triscari, M. (2010) Georisorse del costruito a Messina: una storia di 25 secoli e l’abdicazione ai calcestruzzi armati. In: Accademia Nazionale delle Scienze, “La ricerca scientifica dopo il terremoto siculocalabrese del 1908” Scritti e documenti, XLIII, pp.164-191, Tip. Della Pace Roma. Italy.Zakrzewska, A.M., Capone, P.P., Iannò, A., Tarzia, V., Campopiano, A., Villella, E., Giardino, R. (2008) Calabrian ophiolites: dispersion of airborne asbestos fibers during mining and milling operations, Periodico di Mineralogia, Vol. 77, pp. 27-34.Wood, D.A., Joron, J.L, and Treuil, M. (1979) A re-appraisal of the use of trace element to classify and discriminate between magma series erupted in different tectonic settings, Earth and Planetary Sciences Letters, Vol. 45, pp. 326-336.